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Fomina E. N., Kozlov E. N., Lokhova O. V., Lokhov K. I.
Graphite as an indicator of contact influence of Western Keivy alkaline granite intrusion, the Kola Peninsula
DOI: 10.21443/1560-9278-2017-20-1/1-129-139
- Properties of fluids during metasomatic alteration of metamorphic rocks under P-T conditions of the middle crust: an example from the Bolshie Keivy region, Belomorian-Lapland orogen, Fennoscandian shield
S. А. Bushmin, E. A. Vapnik, М. V. Ivanov, A. В. Kol’tsov, Y. М. Lebedeva, О. V. Aleksandrovich, Е. V. Savva
Петрология, 2024; 32(4): - Properties of Fluids during Metasomatic Alteration of Metamorphic Rocks under P–T Conditions of the Middle Crust: An Example from the Bolshie Keivy Region, Belomorian–Lapland Orogen, Fennoscandian Shield
S. A. Bushmin, Y. A. Vapnik, M. V. Ivanov, A. B. Kol’tsov, Y. M. Lebedeva, O. V. Aleksandrovich, E. V. Savva
Petrology, 2024; 32(4): 478
Abstract. The results of complex petro-mineragraphic, Raman and isotope-geochemical study of three types of graphitebearing rocks circulated at different distances from the alkaline granites: (1) kyanite schists of Bolshiye Keivy, sampled at a considerable distance from a contact with alkaline granites; (2) sillimanite schists, sampled close to the contact, and (3) silexites, located in the inner part of the alkaline granite massif Western Keivy have been presented. Five morphogenetic types of graphite have been revealed in the rocks under consideration: finegrained Gr-1, intergranular Gr-2, nest-shaped Gr-3, vein Gr-4 and spherulitic Gr-5. Current study demonstrates that these five types of graphite distinctly vary not only in morphology, but also in temperature of crystallization, as determined by RSCM-Raman geothermometer, and in carbon isotope composition. The most likely source for the anomalous "light" graphite Gr-1 and Gr-2 [?13C(PDB) = ?43…?45 ‰] from kyanite schists is a watermethane fluid originating from sedimentary rocks with organic compounds. The carbon of graphite Gr-5 of the silexites selected at the inner part of alkaline granite massif Western Keivy, on the contrary, proved to be most "heavy" [?13C(PDB) = ?8 ‰], which indicates its origin from the lower crustal or mantle carbon dioxide fluid. Thus, carbon extracted into the rocks of Keivy structure from at least two contrasting isotope sources. Graphite Gr-3, that makes up the bulk of graphite of exocontact sillimanite schists, is also isotopically light, but not anomalously [?13C(PDB) = ?17…?28 ‰]. The crystallization temperature of the given graphite (435?520 ?C), and its structural relationships with other minerals of the rock evidence of its synmetamorphic origin. The presence of veinlets of isotopically heavy [?13C(PDB) = ?10 ‰…?11 ‰] high-temperature (570?670 ?C) graphite intersecting minerals of the metamorphic paragenesis (including Gr-3) indicates that the introduction of the granites occurred into the previously metamorphosed strata and was accompanied by thermal and fluid influence on these strata.
Keywords: Keivy structure, alkaline granites, graphite, carbon isotope composition, Raman geothermometry
Printed reference: Graphite as an indicator of contact influence of Western Keivy alkaline granite intrusion, the Kola Peninsula / E. Fomina, E. Kozlov, O. Lokhova, K. Lokhov // Vestnik of MSTU. 2017. V. 20, No 1. P. 129-139.
Electronic reference: Graphite as an indicator of contact influence of Western Keivy alkaline granite intrusion, the Kola Peninsula / E. Fomina, E. Kozlov, O. Lokhova, K. Lokhov // Vestnik of MSTU. 2017. V. 20, No 1. P. 129-139. URL: http://vestnik.mstu.edu.ru/v20_1_1n69/13_Fomina_129_139.pdf.
